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ter the fresh air system of the      proved cartridge respirator   5. After cessation of spraying, no
                  building.                            with a prefilter.               person may enter the 50 foot zone
              (e)  Tempered makeup air is recom­    b) In spaces smaller than 2,500    or the enclosed space for at least
                  mended to avoid building nega­       square feet, all persons who    30 minutes unless wearing an ap­
                  tive pressure and to improve         enter the space must wear ap­   proved chemical cartridge respir­
                  general room ventilation.            proved air-supply respirators.  ator, or unless mechanical venti­
              (f)  In some cases, the process equip­  4. The respirator air supply must be   lation has been employed to
                  ment at which diisocyanate leaks   from a source maintained and lo­  insure that isocyanate concentra­
                  may occur is too extensive to be   cated to provide clean respirable   tions are reduced to levels below
                  enclosed by an exhaust hood.      air.
                  In this event, mechanical exhaust
                  and supply ventilation of the en-                                                          —
                  tire room may be necessary.
              (g)  The exhaust systems should be
                  periodically cheeked to insure                                    .<
                  their proper operation.
              Construction and Insulating-1 n-Ptace
            —Investigations conducted in both in­
            door and outdoor locations show that
            there can be a serious isocyanate vapor
            hazard not only to the insulating work­
            ers but to other workers who may be
            in the vicinity. Those who follow the
            insulators on the job can be affected—
            the carpenters, electricians, and other
            tradesmen. In an effort to control the
            insulation workers’ exposure and mini­
            mize the hazard to others, our Occupa­
            tional Health Division, in cooperation
            with representatives of the insulating
            workers, contractors, and isocyanate
            manufacturers, has developed certain
            safeguards.
              Spraying:
              1.  The spray operator and his helper
                 must wear an approved air-supply
                 respirator.
              2.  All other persons located within
                 50 feet of the sprayer must wear
                 approved air-supply respirators.
              3.  a) In spaces larger than 2,500
                    square feet and out-of-doors,
                    persons who enter the 50 foot
                    zone only intermittently or
                    temporarily must wear an ap­  Well Baffjed Hood fer Mold Kelecsse Spraying

                                                             Figure 5
                                                        Isocyanate Samples
                    Number of                    Maximum
             Calendar Industries  Number of    Concentration      Number of Samples at Indicated Concentrations, PPM
              Year  Investigated  Studies Samples  Found    = <.005 >.005-. 01 >.01-.015  >.015-.02  >.02-. 025  = >.026
              1959      3         3      22        0.10       17       1        2                             2
              1960      2         2      11        0.30        2       3        1          1                  4
              1961      2         3      14        0.03       11       2                                      1
              1962      6         8      34        0.83       17       2        1          1         2       11
              1963      4         4      25        0.004      11       2        4          1         1        6
              1964      14       22 100 .          0.11       48      10        1          8         1       32
              1965      10       13      85        0.10       49      15        10         4         2        5
              1966      7        14      105       0.80       52      12        6          5         6       24
              1967      4         5      31        0.03       14      13        2          1                 14
              1968      13       21      112       0.28       59      10        5          5         2       31
              1969      14       19      116       0.07       90       5        4          7         3        7
              Total           i 114     665
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